名称：9-氯甲基蒽
英文名称：9-(Chloromethyl)anthracene
分子式：C15H11Cl
分子量: 226.7
Cas No.：24463-19-2
结构式：
规格：95%
用途：基础原料、有机中间体、医药中间体
合成路线如下：
hydrogenchloride; zinc(II) chloride; water;
Reactants are commercially availlable.
To a stirred solution of anthracene (1.78 g, 10 mmol), anhydrous ZnCl2 (1.64 g, 12 mmol) and paraformaldehyde (1.50 g, 50 mmol) in dioxane (20 mL) was slowly added concentrated aqueous hydrochloric acid (40 mL) at room temperature. The resu lting mixture was gentle refluxed for 3 h and allowed to stand for 16 h at room temperature. The fine granular solid formed was separated by filtration and washed with H2O and dioxane. The crude product was recrystallized from toluene. 1.8 g of a yellowish solid was obtained (64.1 percent yield). 1H NMR (500 MHz, CDCl3): delta 8.40 (m, 4H), 7.62 (m, 4H), 5.61 ppm (s, 4H).
